Basic Information |
|
| Product Name： | TERT-BUTYLDIMETHYLSILYL TRIFLUOROMETHANESULFONATE |
| CAS： | 69739-34-0 |
| English Synonyms： | TRIFLUOROMETHANESULFONIC ACID (1,1-DIMETHYLETHYL)DIMETHYLSILYL ESTER ; (1,1-DIMETHYLETHYL)DIMETHYLSILYL TRIFLUOROMETHANESULFONATE ; TRIFLUOROMETHANESULFONIC ACID T-BUTYLDIMETHYLSILYL ESTER ; TERT-BUTYLDIMETHYLSILYL TRIFLATE ; TRIFLUOROMETHANESULFONIC ACID TERT-BUTYLDIMETHYLSILYL ESTER ; TERT-BUTYLDIMETHYLSILYL TRIFLUOROMETHANESULPHONATE ; CHEMWISH IC20100 ; TERT-BUTYLDIMETHYLSILYL TRIFLUOROMETHANESULFONATE ; SILANE TBM2 TRIFLATE ; ARKPHARMLTD ARK-06493 ; T-BUTYLDIMETHYLSILYL TRIFLUOROMETHANESULFONATE ; TBDMS-OTF ; TBDMS TRIFLATE |
| MDL Number.： | MFCD00000405 |
| H bond acceptor： | 3 |
| H bond donor： | 0 |
| Smile： | FC(S(=O)(=O)O[Si](C)(C)C(C)(C)C)(F)F |
| InChi： | InChI=1S/C7H15F3O3SSi/c1-6(2,3)15(4,5)13-14(11,12)7(8,9)10/h1-5H3 |
| InChiKey： | InChIKey=WLLIXJBWWFGEHT-UHFFFAOYSA-N |
Property |
|
| Boiling Point： | 65-67 DEG C/12 MMHG(LIT)/65-67℃ |
| Density： | DENSITY: 1.151 G/ML AT 25 DEG C(LIT) |
| Physical Property： | FLASHPOINT: 37 DEG C FLASHPOINT: 98.6 DEG F REFRACTIVE INDEX: N20/D 1.385(LIT) |
| Comments： | APPLICATION: THIS REAGENT WAS USED TO INTRODUCE A BULKY TERT-BUTYL DIMETHYLSILYL GROUP ONTO A CIS-BIS(ALKENYL)OXIRANE FACILITATING A ROOM TEMPERATURE COPE REARRANGEMENT TO A 2-CF3-4,5-DIHYDROOXEPIN APPLICATION: TOGETHER WITH A THIOLANE PROMOTES A RAPID AND EFFICIENT CHALCOGENIDE-MORITA-BAYLIS-HILLMAN REACTION RIDADR: UN 2920 8/PG 2 STORAGE TEMPERATURE: 2-8 DEG C UNSPSC: 12352103 WGK: 3 |
| Specification： | REAGENT GRADE |
Safety information |
|
| Symbol： |
GHS02
GHS05
GHS07
|
| Signal word： | Danger |
| Hazard statements： | H226-H314-H335 |
| Precautionary statements： | P261-P280-P305 + P351 + P338-P310 |
| hazard symbol： | C |
| Risk Code： | R:10-34-37 |
| Safe Code： | S:26-36/37/39-45 |
| UN Code： | 2920 |
| WGK Germany： | 3 |
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