TRIPHENYL PHOSPHITE ,101-02-0 _Chemical Cloud Database

TRIPHENYL PHOSPHITE

Basic Information
Product Name：	TRIPHENYL PHOSPHITE
CAS：	101-02-0
English Synonyms：	TRIPHENOXYPHOSPHINE ; TPP ; P(OPH)3 ; (PHO)3P ; TPPI ; PHOSPHOROUS ACID TRIPHENYL ESTER ; TRIPHENYL PHOSPHITE
MDL Number.：	MFCD00003032
H bond acceptor：	3
H bond donor：	0
Smile：	c1ccc(cc1)OP(Oc2ccccc2)Oc3ccccc3
InChi：	InChI=1S/C18H15O3P/c1-4-10-16(11-5-1)19-22(20-17-12-6-2-7-13-17)21-18-14-8-3-9-15-18/h1-15H
InChiKey：	InChIKey=HVLLSGMXQDNUAL-UHFFFAOYSA-N
Property
Melting Point：	22-24 DEG C(LIT)/22-24℃/22-24℃
Boiling Point：	360 DEG C(LIT)/360℃/360℃
Density：	1.184g/mLat25°C(lit.)
Physical Property：	FLASHPOINT: 210 DEG C FLASHPOINT: 410 DEG F REFRACTIVE INDEX: N20/D 1.59(LIT) VAPOR DENSITY: 10.7 (VS AIR) VAPOR PRESSURE: 5 MMHG (205 DEG C)
Comments：	APPLICATION: USED TO CONVERT ALCOHOLS TO ALKYL HALIDES, AS A PEPTIDE COUPLING AGENT, AND, IN COMBINATION WITH OZONE, AS A LOW-TEMPERATURE SOURCE OF SINGLET OXYGEN, AND LIGAND FOR METAL-CATALYZED REACTIONS LIGAND FOR: ALKYLATIONS LIGAND FOR: CYCLOADDITIONS LIGAND FOR: HECK REACTION LIGAND FOR: OLEFINATIONS LIGAND FOR: STILLE COUPLING LIGAND FOR: WITTIG REACTION RIDADR: UN 3077 9/PG 3 UNSPSC: 12352100 WGK: 2
Safety information
Symbol：	GHS07 GHS09
Signal word：	Warning
Hazard statements：	H315-H319-H410
Precautionary statements：	P273-P305 + P351 + P338-P501
hazard symbol：	Xi,N
Risk Code：	R:36/38-50/53
Safe Code：	S:26-61
UN Code：	3077
WGK Germany：	2

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