Basic Information |
|
| Product Name： | 3-(TRIMETHYLSILYLOXY)CROTONIC ACID METHYL ESTER |
| CAS： | 62269-44-7 |
| English Synonyms： | METHYL (2E)-3-[(TRIMETHYLSILYL)OXY]BUT-2-ENOATE ; 3-(TRIMETHYLSILYLOXY)CROTONIC ACID METHYL ESTER ; METHYL 3-(TRIMETHYLSILYLOXY)-2-BUTENOATE ; METHYL 3-(TRIMETHYLSILYLOXY)CROTONATE ; METHYL 3-TRIMETHYLSILOXY-2-BUTENOATE ; METHYL-3-(TRIMETHYLSILOXY)CROTONATE ; 3-(TRIMETHYLSILYLOXY)-2-BUTENOIC ACID METHYL ESTER ; 3-TRIMETHYLSILOXY-2-BUTENOIC ACID METHYL ESTER ; METHYL ACETOACETATE ENOL TRIMETHYLSILYL ETHER |
| MDL Number.： | MFCD00008457 |
| H bond acceptor： | 3 |
| H bond donor： | 0 |
| Smile： | C/C(=C\C(=O)OC)/O[Si](C)(C)C |
| InChi： | InChI=1S/C8H16O3Si/c1-7(6-8(9)10-2)11-12(3,4)5/h6H,1-5H3/b7-6+ |
| InChiKey： | InChIKey=OQNKCUVOGBTGDJ-VOTSOKGWSA-N |
Property |
|
| Boiling Point： | 43-45 DEG C/0.3 MMHG(LIT) |
| Density： | 0.939g/mLat25°C(lit.) |
| Physical Property： | FLASHPOINT: 138.2 DEG F FLASHPOINT: 59 DEG C REFRACTIVE INDEX: N20/D 1.447 |
| Comments： | ASSAY METHOD: TRANS + APPROX 10% CIS OTHER NOTES: A DIENE FOR DIELS-ALDER REACTIONS AND AN EQUIVALENT OF THE DIANIEN OF METHYL ACETOACETATE OTHER NOTES: MILD AND EFFICIENT SILYLATING AGENT OTHER NOTES: STARTING MATERIAL TO 1-METHOXY-1,3-BIS(TRIMETHYLSILOXY)BUTADIENE RIDADR: UN 3272 3/PG 3 STORAGE TEMPERATURE: 2-8 DEG C UNSPSC: 12352100 WGK: 3 |
| Specification： | TECHNICAL GRADE |
Safety information |
|
| Symbol： |
GHS07
|
| Signal word： | Warning |
| Hazard statements： | H315-H319-H335 |
| Precautionary statements： | P261-P305 + P351 + P338 |
| hazard symbol： | Xi |
| Risk Code： | R:36/37/38 |
| Safe Code： | S:26-36/37/39 |
| WGK Germany： | 3 |
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