Basic Information |
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| Product Name： | (ACETYLMETHYLENE)TRIPHENYLPHOSPHORANE |
| CAS： | 1439-36-7 |
| English Synonyms： | (METHYLCARBONYLMETHYLENE)TRIPHENYLPHOSPHORANE ; (2-OXOPROPYLIDENE)TRIPHENYLPHOSPHORANE ; 1-(TRIPHENYL-LAMBDA(5)-PHOSPHANYLIDENE)PROPAN-2-ONE ; (ACETYLMETHYLENE)TRIPHENYLPHOSPHORANE ; 1-TRIPHENYLPHOSPHANYLIDENE-PROPAN-2-ONE ; 1-(TRIPHENYLPHOSPHORANYLIDENE)-2-PROPANONE ; METHYL (TRIPHENYLPHOSPHORANYLIDENE)METHYL KETONE ; 1-(TRIPHENYLPHOSPHORANYLIDENE)ACETONE ; 1-(TRIPHENYLPHOSPHORANYLIDENE)PROPAN-2-ONE ; 2-PROPANONE, 1-(TRIPHENYLPHOSPHORANYLIDENE)- |
| MDL Number.： | MFCD00008774 |
| H bond acceptor： | 1 |
| H bond donor： | 0 |
| Smile： | CC(=O)C=P(c1ccccc1)(c2ccccc2)c3ccccc3 |
| InChi： | InChI=1S/C21H19OP/c1-18(22)17-23(19-11-5-2-6-12-19,20-13-7-3-8-14-20)21-15-9-4-10-16-21/h2-17H,1H3 |
| InChiKey： | InChIKey=KAANTNXREIRLCT-UHFFFAOYSA-N |
Property |
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| Melting Point： | 203-205 DEG C(LIT) |
| Comments： | APPLICATION: REACTANT FOR: CASCADE REACTIONS OF ENALS FOR ENANTIOSELECTIVE SYNTHESIS OF INDANE DERIVATIVES. ENANTIOSELECTIVE CONJUGATE ADDITION FOR SYNTHESIS OF ALPHA-BRANCHED INDOLES. SYNTHESIS OF 1,2-DIOXANES WITH ANTITRYPANOSOMAL ACTIVITY. ASYMMETRIC ALLYLBORATION FOR ENANTIOSELECTIVE SYNTHESIS OF (+)-AWAJANOMYCIN. DOMINO SUZUKI / HECK COUPLING REACTIONS FOR PREPARATION OF FLUORENYLIDENES. SYNTHESIS OF AMPHIBIAN PYRROLIZIDINE ALKALOIDS VIA ALLYLIC AMINATIONS. SYNTHESIS OF SILICON-CONTAINING ACYCLIC DIENONE MUSK ODORANTS APPLICATION: WITTIG REAGENT USED RECENTLY IN THE SYNTHESES OF FUNCTIONALIZED PYRROLIDINES AND CYCLOBUTANONES NSC 407394 RTECS: UC3900000 UNSPSC: 12352103 WGK: 3 |
Safety information |
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| WGK Germany： | 3 |
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