Basic Information |
|
| Product Name： | TRIETHYL PHOSPHONOACETATE |
| CAS： | 867-13-0 ;30492-56-9 |
| English Synonyms： | PHOSPHONOACETIC ACID TRIETHYL ESTER ; ETHYL DIETHYLPHOSPHONOACETATE ; DIETHYL ETHOXYCARBONYLMETHANEPHOSPHONATE ; CARBETHOXYMETHYLDIETHYL PHOSPHONATE ; ACETIC ACID, 2-(DIETHOXYPHOSPHINYL)-, ETHYL ESTER ; (DIETHOXYPHOSPHINYL)ACETIC ACID ETHYL ESTER ; DIETHYLPHOSPHONOACETIC ACID ETHYL ESTER ; PHOSPHONOACETIC ACID ETHYL ESTER ; ETHOXYCARBONYLMETHANEPHOSPHONIC ACID DIETHYL ESTER ; ETHYL 2-(DIETHOXYPHOSPHORYL)ACETATE ; 2-(DIETHOXYPHOSPHINYL)-ACETIC ACID, ETHYL ESTER ; (ETHOXYCARBONYLMETHYL)-DIETHOXYPHOSPHINE OXIDE ; TRIETHYL PHOSPHONOACETATE ; DIETHYL ETHOXYCARBONYLMETHYLPHOSPHONATE ; ETHYL (DIETHOXYPHOSPHORYL)ACETATE ; O,O-DIETHYL ETHOXYCARBONYLMETHYL PHOSPHONATE ; TRIETHYL CARBOXYMETHYLPHOSPHONATE ; TEPA |
| MDL Number.： | MFCD00009177 |
| H bond acceptor： | 5 |
| H bond donor： | 0 |
| Smile： | CCOC(=O)CP(=O)(OCC)OCC |
| InChi： | InChI=1S/C8H17O5P/c1-4-11-8(9)7-14(10,12-5-2)13-6-3/h4-7H2,1-3H3 |
| InChiKey： | InChIKey=GGUBFICZYGKNTD-UHFFFAOYSA-N |
Property |
|
| Melting Point： | -24℃ |
| Boiling Point： | MP: -24 DEG C/142-145 °C |
| Density： | DENSITY: 1.13 G/ML AT 25 DEG C(LIT) |
| Physical Property： | FLASHPOINT: 105 DEG C FLASHPOINT: 221 DEG F REFRACTIVE INDEX: N20/D 1.431(LIT) |
| Comments： | APPLICATION: HORNER-EMMONS-WADSWORTH REAGENT RECENTLY USED IN THE SYNTHESIS OF CHIRAL 2-METHYLCYCLOPROPANECARBOXYLIC ACID FROM (S)-PROPYLENE OXIDE APPLICATION: REACTANT INVOLVED IN: HORNER-WADSWORTH-EMMONS REACTIONS. INTRAMOLECULAR HECK-TYPE CYCLIZATION AND ISOMERIZATIONS. TSUJI-TROST TYPE REACTIONS. INTRAMOLECULAR ARYNE-ENE REACTIONS. SYNTHESIS OF ALDEHYDES NSC 13898 NSC 16128 RIDADR: UN 3082 9/PG 3 RTECS: AG9800000 UNSPSC: 12352103 WGK: 3 |
Safety information |
|
| Symbol： |
GHS09
|
| Hazard statements： | H411 |
| Precautionary statements： | P273 |
| hazard symbol： | N |
| Risk Code： | R:51/53 |
| Safe Code： | S:61 |
| UN Code： | 3082 |
| WGK Germany： | 3 |
| Flash point： | 105℃ |
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