Basic Information |
|
| Product Name： | TRIBUTYL(1-ETHOXYVINYL)TIN |
| CAS： | 97674-02-7 |
| English Synonyms： | TRI-N-BUTYL(1-ETHOXYVINYL)TIN ; TRIBUTYL(1-ETHOXYETHENYL)STANNANE ; TRIBUTYL(1-ETHOXYVINYL)TIN ; 1-ETHOXY-1-(TRIBUTYLSTANNYL)ETHYLENE ; (1-ETHOXYVINYL)TRIBUTYLSTANNANE ; TRIBUTYL(1-ETHOXYVINYL)STANNANE ; 1-ETHOXYVINYL-TRI-N-BUTYLTIN ; 1-ETHOXYVINYLTRIBUTYLTIN ; (1-ETHOXYETHENYL)TRIBUTYLSTANNANE ; (1-ETHOXYVINYL)TRI-N-BUTYLSTANNANE |
| MDL Number.： | MFCD00010240 |
| H bond acceptor： | 1 |
| H bond donor： | 0 |
| Smile： | CCCC[Sn](CCCC)(CCCC)C(=C)OCC |
| InChi： | InChI=1S/C4H7O.3C4H9.Sn/c1-3-5-4-2;3*1-3-4-2;/h1,4H2,2H3;3*1,3-4H2,2H3; |
| InChiKey： | InChIKey=HGXJOXHYPGNVNK-UHFFFAOYSA-N |
Property |
|
| Boiling Point： | 85-86 DEG C/0.1 MMHG(LIT) |
| Density： | 1.069g/mLat25°C(lit.) |
| Physical Property： | FLASHPOINT: 113 DEG C FLASHPOINT: 235.4 DEG F REFRACTIVE INDEX: N20/D 1.476(LIT) |
| Comments： | APPLICATION: ELECTROPHILIC METHYL KETONE EQUIVALENT USED IN A RECENT SYNTHESIS OF A 13-OXOPHORBINE (CHLOROPHYLL) FROM THE CORRESPONDING 13-BROMOCHLORIN APPLICATION: REAGENT EMPLOYED IN PALLADIUM-CATALYZED COUPLING REACTIONS WITH SULFOXIDES, ALPHA-HALOETHERS, AND CHLOROCYCLOBUTENONES. ALSO USED TO CONVERT ACID CHLORIDES TO ALPHA-OXYGENATED ENONES GENERAL DESCRIPTION: THIS VINYLSTANNANE UNDERGOES STILLE COUPLING WITH A VINYL TRIFLATE, GIVING, AFTER HYDROLYSIS, AN ALPHA,BETA-UNSATURATED KETONE, THUS ACTING AS AN ACETYL ANION EQUIVALENT RIDADR: UN 2788 6.1/PG 3 UNSPSC: 12352103 WGK: 3 |
Safety information |
|
| Symbol： |
GHS06
GHS08
GHS09
|
| Signal word： | Danger |
| Hazard statements： | H301-H315-H319-H372-H400 |
| Precautionary statements： | P273-P301 + P310-P305 + P351 + P338-P314 |
| hazard symbol： | T,N |
| Risk Code： | R:21-25-36/38-48/23/25-50/53 |
| Safe Code： | S:35-36/37/39-45-60-61 |
| WGK Germany： | 3 |
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