2-(TRIMETHYLSILYL)ETHOXYMETHYLTRIPHENYLPHOSPHONIUM CHLORIDE ,82495-75-8 _ChemCD

2-(TRIMETHYLSILYL)ETHOXYMETHYLTRIPHENYLPHOSPHONIUM CHLORIDE

basic_info
Product_Name：	2-(TRIMETHYLSILYL)ETHOXYMETHYLTRIPHENYLPHOSPHONIUM CHLORIDE
CAS：	82495-75-8
EnglishSynonyms：	2-(TRIMETHYLSILYL)ETHOXYMETHYLTRIPHENYLPHOSPHONIUM CHLORIDE ; SEM-TRIPHENYLPHOSPHONIUM CHLORIDE ; (TRIMETHYLSILYL)ETHOXYMETHYL TRIPHENYLPHOSPHONIUM CHLORIDE
pro_mdlNumber：	MFCD00043159
pro_acceptors：	1
pro_donors：	0
pro_smile：	C[Si](C)(C)CCOC[P+](c1ccccc1)(c2ccccc2)c3ccccc3.[Cl-]
InChi：	InChI=1S/C24H30OPSi.ClH/c1-27(2,3)20-19-25-21-26(22-13-7-4-8-14-22,23-15-9-5-10-16-23)24-17-11-6-12-18-24;/h4-18H,19-21H2,1-3H3;1H/q+1;/p-1
InChiKey：	InChIKey=NEUMNYXEDIPGJD-UHFFFAOYSA-M
property
MeltingPoint：	145-149 DEG C(LIT)
Comments：	APPLICATION: REACTANT FOR: ENANTIOSELECTIVE SYNTHESIS OF (-)-SARAIN A USING ASYMMETRIC MICHAEL ADDITION, CYCLIZATION, RING-CLOSING METATHESIS, INTRAMOLECULAR STILLE COUPLING, AND LATE-STATE INSTALLATION OF TERTIARY AMINE-ALDEHYDE PROXIMITY INTERACTION. PREPARATION OF ALIPHATIC AND ALICYCLIC ALDEHYDES BY HOMOLOGATION OF ALDEHYDES. WITTIG REACTIONS. PREPARATION OF OPTICALLY ACTIVE (1S,5R)-(+)-3-AZABICYCLO[3.2.2]NON-6-EN-2-ONE VIA ENANTIOSELECTIVE INTRAMOLECULAR CYCLOPROPANATION UNSPSC: 12352103 WGK: 3
secure_info
secure_symbol：	GHS07
secure_signal_word：	Warning
secure_risk_stmt：	H315-H319-H335
secure_cautionary_stmt：	P261-P305 + P351 + P338
secure_damage_code：	Xi
secure_risk_disclosure_stmt：	R:36/37/38
secure_security_stmt：	S:26-36
secure_wgk_germany：	3

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