Basic Information |
|
| Product Name： | COPPER(I) TRIFLUOROMETHANESULFONATE BENZENE COMPLEX |
| CAS： | 42152-46-5 ;37234-97-2 |
| English Synonyms： | BIS[COPPER (I) TRIFLUOROMETHANESULFONATE], BENZENE COMPLEX ; CUPROUS TRIFLUOROMETHANESULFONATE BENZENE COMPLEX ; COPPER(I) TRIFLATE BENZENE COMPLEX ; BIS[COPPER(I) TRIFLUOROMETHANESULFONATE] BENZENE COMPLEX (2:1) ; COPPER(I) TRIFLUOROMETHANESULFONATE BENZENE COMPLEX ; COPPER(I) TRIFLUOROMETHANESULFONATE BENZENE COMPLEX (2:1) ; TRIFLUOROMETHANESULFONIC ACID COPPER(I) SALT BENZENE COMPLEX ; COPPER(I) TRIFLATE BENZENE COMPLEX (2:1) |
| MDL Number.： | MFCD00043300 |
| H bond acceptor： | 3 |
| H bond donor： | 0 |
| Smile： | c1ccccc1.C(F)(F)(F)S(=O)(=O)[O-].C(F)(F)(F)S(=O)(=O)[O-].[Cu+].[Cu+] |
| InChi： | InChI=1S/C6H6.2CHF3O3S.2Cu/c1-2-4-6-5-3-1;2*2-1(3,4)8(5,6)7;;/h1-6H;2*(H,5,6,7);;/q;;;2*+1/p-2 |
| InChiKey： | InChIKey=GNXZWVVAAMVOJY-UHFFFAOYSA-L |
Property |
|
| Melting Point： | 160 DEG C (DEC)(LIT) |
| Physical Property： | FLASHPOINT: 44.6 DEG F FLASHPOINT: 7 DEG C |
| Comments： | APPLICATION: IN COMBINATION WITH AMINO ACID-BASED CHIRAL PHOSPHINE LIGANDS, CATALYZES ASYMMETRIC CONJUGATE ADDITIONS OF ALKYLZINCS TO ACYCLIC ALPHA,BETA-UNSATURATED KETONES, AFFORDING BETA-ALKYLCARBONYLS IN HIGH YIELD AND WITH EXCELLENT ENANTIOSELECTIVITY. CATALYZES ALLYLIC OXIDATION OF CYCLIC ALKENES ENANTIOSELECTIVELY RIDADR: UN 3175 4.1/PG 2 UNSPSC: 12352300 WGK: 3 |
| Specification： | TECHNICAL GRADE |
Safety information |
|
| Symbol： |
GHS02
GHS07
|
| Signal word： | Danger |
| Hazard statements： | H225-H315-H319-H335 |
| Precautionary statements： | P210-P261-P305 + P351 + P338 |
| hazard symbol： | F |
| Risk Code： | R:11-36/37/38 |
| Safe Code： | S:16-26-36 |
| WGK Germany： | 3 |
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