LITHIUM DIISOPROPYLAMIDE ,4111-54-0

LITHIUM DIISOPROPYLAMIDE

Basic Information
Product Name：	LITHIUM DIISOPROPYLAMIDE
CAS：	4111-54-0
English Synonyms：	LDA THF COMPLEX ; LDA ; DIISOPROPYLAMINOLITHIUM ; LITHIUM DIISOPROPYLAMIDE ; LITHIUM DIISOPROPYLAMIDE SOLUTION
MDL Number.：	MFCD00064449
H bond acceptor：	1
H bond donor：	0
Smile：	[Li]N(C(C)C)C(C)C
InChi：	InChI=1S/C6H14N.Li/c1-5(2)7-6(3)4;/h5-6H,1-4H3;/q-1;+1
InChiKey：	InChIKey=ZCSHNCUQKCANBX-UHFFFAOYSA-N
Property
Boiling Point：	60-136℃
Density：	0.812g/mLat25°C
Physical Property：	FLASHPOINT: 2 DEG C FLASHPOINT: 35.6 DEG F
Comments：	APPLICATION: TITANIUM-ATE ENOLATES PREPARED FROM KETONES BY TI(OIPR)4 AND LDA UNDERWENT EFFICIENT RADICAL TRIFLUOROMETHYLATION PROVIDING TRIFLUOROMETHYL KETONES IN GOOD YIELD. USED IN DIRECTED ORTHO-LITHIATION OF ARYLSULFONYLOXAZOLIDINONES TO PREPARE N-SUBSTITUTED SACCHARIN ANALOGS CONCENTRATION: 2.0 M IN THF/HEPTANE/ETHYLBENZENE FORM: SOLUTION IMPURITIES: 3 WT% DIISOPROPYLAMINE ORIGINAL SKU: 361798-4X25ML RIDADR: UN 3399 4.3/PG 2 STORAGE TEMPERATURE: 2-8 DEG C UNSPSC: 12352103 WGK: 3
Concentration：	2.0MinTHF/heptane/ethylbenzene
Safety information
Symbol：	GHS02 GHS05 GHS07 GHS08 GHS09
Signal word：	Danger
Hazard statements：	H225-H304-H314-H335-H336-H351-H361-H411
Precautionary statements：	P210-P261-P273-P280-P301 + P310-P305 + P351 + P338
hazard symbol：	F,C,N
Risk Code：	R:63-11-14-17-19-34-37-40-51/53-62-65-67
Safe Code：	S:16-26-36/37/39-43-45-61-62
WGK Germany：	3
Flash point：	-18 °C

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