(TERT-BUTOXYCARBONYLMETHYL)TRIPHENYLPHOSPHONIUM BROMIDE ,59159-39-6 _ChemCD

(TERT-BUTOXYCARBONYLMETHYL)TRIPHENYLPHOSPHONIUM BROMIDE

basic_info
Product_Name：	(TERT-BUTOXYCARBONYLMETHYL)TRIPHENYLPHOSPHONIUM BROMIDE
CAS：	59159-39-6
EnglishSynonyms：	(TERT-BUTOXYCARBONYLMETHYL)TRIPHENYLPHOSPHANIUM BROMIDE ; (TERT-BUTOXYCARBONYLMETHYL)TRIPHENYLPHOSPHONIUM BROMIDE ; TRIPHENYL TERT BUTOXYCARBONYL METHYL PHOSPHONIUM BROMIDE ; CARBO-TERT-BUTOXYMETHYL TRIPHENYLPHOSPHONIUM BROMIDE
pro_mdlNumber：	MFCD00075527
pro_acceptors：	2
pro_donors：	0
pro_smile：	CC(C)(C)OC(=O)C[P+](c1ccccc1)(c2ccccc2)c3ccccc3.[Br-]
InChi：	InChI=1S/C24H26O2P.BrH/c1-24(2,3)26-23(25)19-27(20-13-7-4-8-14-20,21-15-9-5-10-16-21)22-17-11-6-12-18-22;/h4-18H,19H2,1-3H3;1H/q+1;/p-1
InChiKey：	InChIKey=ZGLFRTJDWWKIAK-UHFFFAOYSA-M
property
MeltingPoint：	178 DEG C (DEC)(LIT)
Comments：	APPLICATION: REACTANT FOR: RHODIUM-CATALYZED ASYMMETRIC HYDROGENATION REACTIONS. WITTIG REACTION. WITTIG METHYLENATION. PREPARATION OF N-(PHENYLMETHYL)-CIS-PYRROLIDINEDIACETIC ACID ESTERS VIA DOUBLE AZA-MICHAEL ADDITION REACTION. STEREOSELECTIVE PREPARATION OF OF ALPHA-FLUORO-ALPHA,BETA-UNSATURATED ESTERS VIA DEPROTONATION, FOLLOWED BY FLUORINATION AND STEREOSELECTIVE WITTIG OLEFINATION WITH ALDEHYDES. WITTIG CHAIN EXTENSION REACTIONS NSC 82468 UNSPSC: 12352100 WGK: 3
secure_info
secure_symbol：	GHS07
secure_signal_word：	Warning
secure_risk_stmt：	H315-H319-H335
secure_cautionary_stmt：	P261-P305 + P351 + P338
secure_damage_code：	Xi
secure_risk_disclosure_stmt：	R:36/37/38
secure_security_stmt：	S:26-37/39
secure_wgk_germany：	3

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