Basic Information |
|
| Product Name： | (TERT-BUTOXYCARBONYLMETHYLENE)TRIPHENYLPHOSPHORANE |
| CAS： | 35000-38-5 |
| English Synonyms： | (CARBO-TERT-BUTOXYMETHYLENE)TRIPHENYLPHOSPHORANE ; (TRIPHENYL-LAMBDA5-PHOSPHANYLIDENE)-ACETIC ACID TERT-BUTYL ESTER ; TRIPHENYLPHORANYLIDENE ACETIC ACID 1,1-DIMETHYLETHYL ESTER ; TERT-BUTYL(TRIPHENYLPHOSPHORANYLIDENE)ACETATE ; ACETIC ACID, 2-(TRIPHENYLPHOSPHORANYLIDENE)-, 1,1-DIMETHYLETHYL ESTER ; TERT-BUTYL 2-(TRIPHENYLPHOSPHORANYLIDENE)ACETATE ; TRIPHENYLPHOSPHORANYLIDENE ACETIC ACID 1,1-DIMETHYLETHYL ESTER ; (TRIPHENYLPHOSPHORANYLIDENE) TERT-BUTYL ACETATE ; (TERT-BUTOXYCARBONYLMETHYLENE)TRIPHENYLPHOSPHORANE |
| MDL Number.： | MFCD00075545 |
| H bond acceptor： | 2 |
| H bond donor： | 0 |
| Smile： | CC(C)(C)OC(=O)C=P(c1ccccc1)(c2ccccc2)c3ccccc3 |
| InChi： | InChI=1S/C24H25O2P/c1-24(2,3)26-23(25)19-27(20-13-7-4-8-14-20,21-15-9-5-10-16-21)22-17-11-6-12-18-22/h4-19H,1-3H3 |
| InChiKey： | InChIKey=ZWZUFQPXYVYAFO-UHFFFAOYSA-N |
Property |
|
| Melting Point： | 152-155 DEG C(LIT) |
| Comments： | APPLICATION: WITTIG REAGENT USED IN THE SYNTHESIS OF ALDOSE REDUCTASE INHIBITORS, A PODOPHYLLOTOXIN DERIVATIVE AND TAUTOMYCIN. VERSATILE WITTIG REAGENT USED IN MEDICINAL CHEMISTRY RIDADR: UN 3464 6.1/PG 2 STORAGE TEMPERATURE: 2-8 DEG C UNSPSC: 12352103 WGK: 3 |
Safety information |
|
| Symbol： |
GHS06
GHS08
GHS09
|
| Signal word： | Danger |
| Hazard statements： | H301-H317-H319-H373-H411 |
| Precautionary statements： | P273-P280-P301 + P310-P305 + P351 + P338 |
| hazard symbol： | T,N |
| Risk Code： | R:25-36-43-48/22-51/53 |
| Safe Code： | S:26-36/37/39-45-61 |
| WGK Germany： | 3 |
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