Basic Information |
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| Product Name： | PYBROP |
| CAS： | 132705-51-2 |
| English Synonyms： | BROMO-TRIS-PYRROLIDINO- ; PYBROP ; PYBROP HEXAFLUOROPHOSPHATE ; PYBROP(R) ; BROMO-TRIS-PYRROLIDINO-PHOSPHONIUM HEXAFLUOROPHOSPHATE ; BROMOTRIS(PYRROLIDIN-1-YL)PHOSPHANIUM, HEXAFLUORO-LAMBDA(5)-PHOSPHANUIDE ; PYBROP(R) HEXAFLUOROPHOSPHATE ; BROMOTRI(1-PYRROLIDINYL)PHOSPHONIUM HEXAFLUOROPHOSPHATE ; BROMO-TRIS-PYRROLIDINOPHOSPHONIUM HEXAFLUOROPHOSPHATE ; BROMOTRI(PYRROLIDIN-1-YL)PHOSPHONIUM HEXAFLUOROPHOSPHATE(V) ; BROMOTRI(PYRROLIDIN-1-YL)PHOSPHONIUM HEXAFLUOROPHOSPHATE ; BROMOTRIPYRROLIDINOPHOSPHONIUM HEXAFLUOROPHOSPHATE |
| MDL Number.： | MFCD00077412 |
| H bond acceptor： | 3 |
| H bond donor： | 0 |
| Smile： | C1CCN(C1)[P+](N2CCCC2)(N3CCCC3)Br.F[P-](F)(F)(F)(F)F |
| InChi： | InChI=1S/C12H24BrN3P.F6P/c13-17(14-7-1-2-8-14,15-9-3-4-10-15)16-11-5-6-12-16;1-7(2,3,4,5)6/h1-12H2;/q+1;-1 |
| InChiKey： | InChIKey=CYKRMWNZYOIJCH-UHFFFAOYSA-N |
Property |
|
| Melting Point： | >100℃ |
| Comments： | APPLICATION: CATALYST FOR: SYNTHESIS OF PRIMARY AMIDES. DIRECT DEHYDRATIVE PHOSPHONIUM CROSS COUPLING. DIRECT ARYLATION. PYRROLIDIDE FORMATION BY PHOSPHONIUM SALT COUPLING REAGENTS ASSAY METHOD: HPLC LEGAL INFORMATION: PYBROP IS A REGISTERED TRADEMARK OF MERCK KGAA OTHER NOTES: REACTIVE PEPTIDE COUPLING REAGENT SUITABLE FOR ALPHA,ALPHA-DIALKYL AMINO ACIDS OTHER NOTES: SYNTHESIS OF DEPSIPEPTIDES STORAGE TEMPERATURE: -20 DEG C UNSPSC: 12352100 WGK: 3 |
Safety information |
|
| Symbol： |
GHS05
|
| Signal word： | Danger |
| Hazard statements： | H314 |
| Precautionary statements： | P280-P305 + P351 + P338-P310 |
| hazard symbol： | C |
| Risk Code： | R:34 |
| Safe Code： | S:26-27-36/37/39-45 |
| WGK Germany： | 3 |
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