Basic Information |
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| Product Name： | N-FLUOROBENZENESULFONIMIDE |
| CAS： | 133745-75-2 |
| English Synonyms： | ACCUFLUOR(R) NFSI ; N-FLUORODIBENZENESULPHONIMIDE ; ACCUFLUOR NFSI ; N-FLUOROBENZENSULFONIMIDE ; N-FLUOROBIS(PHENYLSULPHONYL)AMINE ; N-FLUOROBIS(PHENYLSULFONYL)AMINE ; BIS(PHENYLSULPHONYL)(FLUORO)AMINE ; N-FLUORODIBENZENESULFONAMIDE ; BIS(PHENYLSULFONYL)FLUOROAMINE ; N-FLUOROBENZENESULFONIMIDE ; N-FLUORODIBENZENESULFONIMIDE ; BENZENESULFONAMIDE, N-FLUORO-N-(PHENYLSULFONYL)- ; N-FLUORODI(BENZENESULFONYL)AMINE ; N-FLUOROBENZENESULPHONIMIDE ; NFSI ; N-FLUORO-N-(PHENYLSULFONYL)BENZENESULFONAMIDE ; N-FLUORO-N-(PHENYLSULPHONYL)BENZENESULPHONAMIDE ; N-(BENZENESULFONYL)-S-PHENYLFLUORANESULFONAMIDO |
| MDL Number.： | MFCD00144885 |
| H bond acceptor： | 5 |
| H bond donor： | 0 |
| Smile： | c1ccc(cc1)S(=O)(=O)N(F)S(=O)(=O)c2ccccc2 |
| InChi： | InChI=1S/C12H10FNO4S2/c13-14(19(15,16)11-7-3-1-4-8-11)20(17,18)12-9-5-2-6-10-12/h1-10H |
| InChiKey： | InChIKey=RLKHFSNWQCZBDC-UHFFFAOYSA-N |
Property |
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| Melting Point： | 110 DEG C (DEC)(LIT)/115°C |
| Comments： | APPLICATION: REAGENT EMPLOYED IN A PALLADIUM-CATALYZED ENANTIOSELECTIVE FLUORINATION OF T-BUTOXYCARBONYL LACTONES AND LACTAMS. ALSO USED IN THE ELECTROPHILIC DIFLUORINATION OF DIHALOPYRIDINES WITH BUTYL LITHIUM AND IN THE DIRECT CONVERSION OF ALCOHOLS TO DIBENZENESULFONAMIDES WITH TRIPHENYLPHOSPHINE APPLICATION: STABLE, EASY-TO-HANDLE, CRYSTALLINE MATERIAL WHICH READILY TRANSFERS F+ TO ENOLATES AND CARBANIONS UNSPSC: 12352100 WGK: 3 |
Safety information |
|
| Symbol： |
GHS07
|
| Signal word： | Warning |
| Hazard statements： | H315-H319-H335 |
| Precautionary statements： | P261-P305 + P351 + P338 |
| hazard symbol： | Xi |
| Risk Code： | R:36/37/38 |
| Safe Code： | S:26 |
| WGK Germany： | 3 |
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