Basic Information |
|
| Product Name： | PHOSPHAZENE BASE P4-T-BU |
| CAS： | 111324-04-0 |
| English Synonyms： | PHOSPHAZENE BASE P4-T-BU ; 1-TERT-BUTYL-4,4,4-TRIS(DIMETHYLAMINO)-2,2-BIS[TRIS(DIMETHYLAMINO)-PHOSPHORANYLIDENAMINO]-2LAMBDA5,4LAMBDA5-CATENADI(PHOSPHAZENE) |
| MDL Number.： | MFCD00145114 |
| H bond acceptor： | 13 |
| H bond donor： | 0 |
| Smile： | CC(C)(C)N=P(N=P(N(C)C)(N(C)C)N(C)C)(N=P(N(C)C)(N(C)C)N(C)C)N=P(N(C)C)(N(C)C)N(C)C |
| InChi： | InChI=1S/C22H63N13P4/c1-22(2,3)23-36(24-37(27(4)5,28(6)7)29(8)9,25-38(30(10)11,31(12)13)32(14)15)26-39(33(16)17,34(18)19)35(20)21/h1-21H3 |
| InChiKey： | InChIKey=NSRBCQCXZAYQHF-UHFFFAOYSA-N |
Property |
|
| Density： | DENSITY: 0.90 G/ML AT 20 DEG C |
| Physical Property： | FLASHPOINT: -14.8 DEG F FLASHPOINT: -26 DEG C |
| Comments： | APPLICATION: PHOSPHAZENE BASES: A FAMILY OF EXTREMELY STRONG, NON-IONIC, NON-CHARGED NITROGEN-BASES CAUTION: PRODUCT CRYSTALLIZES OUT OF SOLUTION, CAN BE REDISSOLVED ON HEATING TO 40 DEG C CONCENTRATION: APPROX 1.0 M IN HEXANE FORM: SOLUTION OTHER NOTES: BASE FOR ENOLATE FORMATION AND STEREOSELECTIVE ALKYLATION OTHER NOTES: EXTREMELY STRONG, HINDERED, NEUTRAL NITROGEN BASE OTHER NOTES: IT IS ABOUT 1018 TIMES MORE BASIC THAN DBU [PKA (DMSO) 30.25]. STABLE TO HYDROLYSIS AND UNAFFECTED BY ALKYLATING AGENTS RIDADR: UN 2924 3/PG 2 UNSPSC: 12352100 WGK: 3 |
| Concentration： | APPROX 1.0 M IN HEXANE |
Safety information |
|
| Symbol： |
GHS02
GHS05
GHS07
GHS08
|
| Signal word： | Danger |
| Hazard statements： | H225-H304-H314-H336-H361f-H373-H412 |
| Precautionary statements： | P210-P261-P273-P280-P301 + P310-P305 + P351 + P338 |
| hazard symbol： | F,C |
| Risk Code： | R:11-34-48/20-52/53-62-65-67 |
| Safe Code： | S:16-26-36/37/39-45-61-62 |
| WGK Germany： | 3 |
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