Basic Information |
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| Product Name： | (TRIPHENYLPHOSPHINE)COPPER HYDRIDE HEXAMER |
| CAS： | 33636-93-0 |
| English Synonyms： | HYDRIDO(TRIPHENYLPHOSPHINE)COPPER(I) HEXAMER ; CUPROUS HYDRIDE TRIPHENYLPHOSPHINE HEXAMER ; (TRIPHENYLPHOSPHINE)COPPER HYDRIDE HEXAMER ; TRIPHENYLPHOSPHINE-COPPER(I) HYDRIDE HEXAMER ; STRYKER'S REAGENT ; TRIPHENYLPHOSPHINE COPPER(I) HYDRIDE |
| MDL Number.： | MFCD00221518 |
| H bond acceptor： | 0 |
| H bond donor： | 0 |
| Smile： | c1ccc(cc1)P(c2ccccc2)c3ccccc3.c1ccc(cc1)P(c2ccccc2)c3ccccc3.c1ccc(cc1)P(c2ccccc2)c3ccccc3.c1ccc(cc1)P(c2ccccc2)c3ccccc3.c1ccc(cc1)P(c2ccccc2)c3ccccc3.c1ccc(cc1)P(c2ccccc2)c3ccccc3.[CuH].[CuH].[CuH].[CuH].[CuH].[CuH] |
| InChi： | InChI=1S/6C18H15P.6Cu.6H/c6*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;;;;;;;;;;/h6*1-15H;;;;;;;;;;;; |
| InChiKey： | InChIKey=PYHLOCIDGQNZFY-UHFFFAOYSA-N |
Property |
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| Comments： | APPLICATION: CATALYST FOR: CONJUGATE REDUCTION OF ORTHO-SUBSTITUTED CINNAMIC ESTERS TO FORM COPPER ENOLATES. CHEMOSELECTIVE PREPARATION OF ALCOHOLS VIA HYDROGENATION OF ALDEHYDES. 1,2-ADDITION/TRANSMETALATION REACTIONS. SYNTHESIS OF MONOMER FOR PREPARATION OF PHOSPHORUS- AND SILICON-CONTAINING EPOXY RESINS. HYDROSILYLATION REACTIONS. CHIRAL HYDROGENATION REACTIONS. HYDROSTANNATION OF ACTIVATED ALKYNES APPLICATION: USEFUL SYNTHETIC APPLICATIONS INCLUDE STOICHIOMETRIC AND CATALYTIC HYDROGENATIONS, CHEMOSELECTIVE CONJUGATE REDUCTIONS, AS WELL AS REGIOSPECIFIC AND STEREOSELECTIVECONJUGATE HYDRIDE REDUCTIONS UNSPSC: 12352103 WGK: 3 |
Safety information |
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| Symbol： |
GHS07
|
| Signal word： | Warning |
| Hazard statements： | H315-H319-H335 |
| Precautionary statements： | P261-P305 + P351 + P338 |
| hazard symbol： | Xi |
| Risk Code： | R:36/37/38 |
| Safe Code： | S:26-36 |
| WGK Germany： | 3 |
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