(R,R)-(-)N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINOMANGANESE(III) CHLORIDE ,138124-32-0

(R,R)-(-)N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINOMANGANESE(III) CHLORIDE

CAS No.: 138124-32-0
CCD No.: CCD00289286
Formula: C36 H52 Cl Mn N2 O2
MolWeight: 635.21

Basic Information
Product Name：	(R,R)-(-)N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINOMANGANESE(III) CHLORIDE
CAS：	138124-32-0
English Synonyms：	(R,R)-(-)N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINOMANGANESE(III) CHLORIDE ; JACOBSEN'S CATALYST ; (R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLID ENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(I)CHLORIDE ; (R,R)-JACOBSEN'S CATALYST ; (1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N,N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]MANGANESE (III) CHLORIDE ; (R,R)-JACOBSEN CAT ; (R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINE-MANGANESE(III) CHLORIDE ; (R,R)-JACOBSEN CATALYST ; (1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N,N'-BIS-(3,5-DI-TERT-BUTYLSALICYDENE)] MANGANESE(III)CHLORIDE ; (R,R)-JACOBSEN'S CATALYST MANGANESE(III) CHLORIDE COMPLEX
MDL Number.：	MFCD02101664
H bond acceptor：	4
H bond donor：	0
Smile：	CC(C)(C)c1cc\2c(c(c1)C(C)(C)C)O[Mn](Oc3c(cc(cc3C(C)(C)C)C(C)(C)C)/C=N/[C@@H]4CCCC[C@H]4/N=C2)Cl
InChi：	InChI=1S/C36H54N2O2.ClH.Mn/c1-33(2,3)25-17-23(31(39)27(19-25)35(7,8)9)21-37-29-15-13-14-16-30(29)38-22-24-18-26(34(4,5)6)20-28(32(24)40)36(10,11)12;;/h17-22,29-30,39-40H,13-16H2,1-12H3;1H;/q;;+3/p-3/b37-21+,38-22+;;/t29-,30-;;/m1../s1
InChiKey：	InChIKey=LJVAWOSDJSQANR-OHRASPNLSA-K
Property
Melting Point：	330-332 DEG C(LIT)
Comments：	APPLICATION: SALEN (MN)-CATALYZED ASYMMETRIC EPOXIDATION OF UNFUNCTIONALIZED OLEFINS. HIGH ENANTIOSELECTIVITIES AND YIELDS ARE OBTAINED FOR A VARIETY OF SUBSTRATES, ESPECIALLY CIS-ALKENES. A FEW APPLICATIONS INCLUDE THE SYNTHESIS OF THE TAXOL SIDE CHAIN AND CIS-1-AMINO-2-INDANOL. JACOBSEN'S CATALYST HAS ALSO BEEN USED IN THE ASYMMETRIC ALPHA-HYDROXYLATION OF SILYL ENOL ETHERS. CATALYST FOR THE ENANTIOSELECTIVE EPOXIDATION OF A VARIETY OF OLEFINS LEGAL INFORMATION: MANUFACTURED UNDER LICENSE BY SHASUN CHEMICALS AND DRUGS LIMITED, USING JACOBSEN HKR TECHNOLOGY UNSPSC: 12352100 WGK: 3
Safety information
Symbol：	GHS07
Signal word：	Warning
Hazard statements：	H315-H319-H335
Precautionary statements：	P261-P305 + P351 + P338
hazard symbol：	Xi
Risk Code：	R:36/37/38
Safe Code：	S:26-36
WGK Germany：	3

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(R,R)-(-)N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINOMANGANESE(III) CHLORIDE

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