Basic Information |
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| Product Name： | HOVEYDA-GRUBBS CATALYST 1ST GENERATION |
| CAS： | 203714-71-0 |
| English Synonyms： | DICHLORO[[2-(1-METHYLETHOXY-O)PHENYL]METHYLENE](TRICYCLOHEXYLPHOSPHINE)RUTHENIUM ; RUTHENIUM, DICHLORO[[2-(1-METHYLETHOXY)PHENYL]METHYLENE](TRICYCLOHEXYLPHOSPHINE) ; HOVEYDA-GRUBBS CATALYST 1ST GENERATION ; DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE)(TRICYCLOHEXYLPHOSPHINE)RUTHENIUM(II) |
| MDL Number.： | MFCD03453042 |
| H bond acceptor： | 1 |
| H bond donor： | 0 |
| Smile： | CC(C)Oc1ccccc1C=[Ru](Cl)Cl.C1CCC(CC1)P(C2CCCCC2)C3CCCCC3 |
| InChi： | InChI=1S/C18H33P.C10H12O.2ClH.Ru/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-8(2)11-10-7-5-4-6-9(10)3;;;/h16-18H,1-15H2;3-8H,1-2H3;2*1H;/q;;;;+2/p-2 |
| InChiKey： | InChIKey=KMKCJXPECJFQPQ-UHFFFAOYSA-L |
Property |
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| Melting Point： | 195-197 DEG C(LIT) |
| Comments： | APPLICATION: HOVEYDA-GRUBBS 1ST GENERATION CATALYSTSIMILAR REACTIVITY TO THE GRUBBS 1ST GENERATION CATALYST. PROVEN TO BE USEFUL IN RING-CLOSING METATHESIS (RCM) TO FORM MACROCYCLES.CATALYST USED IN RING-CLOSING METATHESIS WITH CONCOMITANT CIS-VICINAL DIHYROXYLATION. ALSO EMPLOYED IN A PIVOTAL, MACROCYCLIC RING-CLOSING METATHESIS IN THE MULTI-STEP SYNTHESIS OF AN HCV PROTEASE INHIBITOR APPLICATION: METATHESIS: RUTHENIUM-BASED METATHESIS CATALYSTS APPLICATION: OLEFIN METATHESIS CATALYST LEGAL INFORMATION: SALE OF THIS PRODUCT CONVEYS TO THE BUYER A LIMITED-USE RESEARCH LICENSE. FOR FULL DETAILS OF THIS LICENSE PLEASE SEE SIGMA-ALDRICH.COM/MATERIALICENSE. FOR QUESTIONS, PLEASE CONTACT US AT ALDRICH AT SIAL.COM OR MATERIA AT INFO AT MATERIA-INC.COM OTHER NOTES: NO BULK ORDERS STORAGE TEMPERATURE: 2-8 DEG C UNSPSC: 12352103 WGK: 3 |
Safety information |
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| Symbol： |
GHS02
|
| Signal word： | Warning |
| Hazard statements： | H228 |
| Precautionary statements： | P210 |
| hazard symbol： | F |
| Risk Code： | R:11 |
| WGK Germany： | 3 |
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