basic_info |
|
| Product_Name： | DICHLORO(3-METHYL-2-BUTENYLIDENE)BIS(TRICYCLOHEXYLPHOSPHINE)RUTHENIUM(II) |
| CAS： | 194659-03-5 |
| EnglishSynonyms： | DICHLORO(3-METHYL-2-BUTENYLIDENE)BIS(TRICYCLOHEXYLPHOSPHINE)RUTHENIUM(II) ; BIS(TRICYCLOHEXYLPHOSPHINE)ISOPENTENYLIDENE RUTHENIUM DICHLORIDE ; GRUBBS CATALYST 801 |
| pro_mdlNumber： | MFCD04039970 |
| pro_acceptors： | 0 |
| pro_donors： | 0 |
| pro_smile： | C[C](C)[CH][CH].C1CCC(CC1)P(C2CCCCC2)C3CCCCC3.C1CCC(CC1)P(C2CCCCC2)C3CCCCC3.Cl[Ru]Cl |
| InChi： | InChI=1S/2C18H33P.C5H8.2ClH.Ru/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-4-5(2)3;;;/h2*16-18H,1-15H2;1,4H,2-3H3;2*1H;/q;;;;;+2/p-2 |
| InChiKey： | InChIKey=INCDKKABOVOFIV-UHFFFAOYSA-L |
property |
|
| MeltingPoint： | 160-165 DEG C(LIT) |
| Comments： | APPLICATION: KINETIC APPLICATION PROFILE SIMILAR TO THAT OF GRUBBS 1ST GENERATION CATALYST APPLICATION: METATHESIS: RUTHENIUM-BASED METATHESIS CATALYSTSCATALYST FOR: OLEFIN METATHESIS (SCHIFF BASE CATALYST). POLYMERIZATION REACTIONS. CROSS METATHESIS REACTIONS. RING-CLOSING METATHESIS. DEHYDRATION REACTIONS. SOLVENTLESS RING-OPENING METATHESIS POLYMERIZATION OF NORBORNENE DERIVATIVES TO FORM POLYMERIC THIN FILMS. USED FOR PREPARATION OF SECOND GENERATION GRUBBS CATALYSTS LEGAL INFORMATION: US PATENT NO 5,969,170 (AND ASSOCIATED FOREIGN EQUIVALENTS OF THE FOREGOING) APPLY. SALE OF THIS PRODUCT CONVEYS TO THE BUYER A LIMITED-USE RESEARCH LICENSE. FOR FULL DETAILS OF THIS LICENSE PLEASE SEE SIGMA-ALDRICH.COM/MATERIALICENSE. FOR QUESTIONS, PLEASE CONTACT US AT ALDRICH AT SIAL.COM OR MATERIA AT INFO AT MATERIA-INC.COM OTHER NOTES: NO BULK ORDERS STORAGE TEMPERATURE: 2-8 DEG C UNSPSC: 12352103 WGK: 3 |
secure_info |
|
| secure_symbol： |
GHS02
|
| secure_signal_word： | Warning |
| secure_risk_stmt： | H228 |
| secure_cautionary_stmt： | P210 |
| secure_wgk_germany： | 3 |
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