(+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS) ,490023-37-5

(+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS)

Basic Information
Product Name：	(+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS)
CAS：	490023-37-5
English Synonyms：	(S)-(+)-BENZYL(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)METHYLAMINE ; (+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS) ; (S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BENZYL(METHYL)AMINE ; (S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A3,4-A']DINAPHTHALEN-4-YL)BENZYL(METHYL)AMINE
MDL Number.：	MFCD04117686
H bond acceptor：	3
H bond donor：	0
Smile：	CN(Cc1ccccc1)p2oc3ccc4ccccc4c3c5c6ccccc6ccc5o2
InChi：	InChI=1S/C28H22NO2P/c1-29(19-20-9-3-2-4-10-20)32-30-25-17-15-21-11-5-7-13-23(21)27(25)28-24-14-8-6-12-22(24)16-18-26(28)31-32/h2-18H,19H2,1H3
InChiKey：	InChIKey=OHGGHRJGBXAKKY-UHFFFAOYSA-N
Property
Melting Point：	155-159 DEG C
Comments：	APPLICATION: DSM MONOPHOS FAMILY OF HIGHLY EFFICIENT PRIVILEGED LIGANDS APPLICATION: PHOSPHORAMIDITE LIGAND USED IN A RHODIUM-CATALYZED ENANTIOSELECTIVE 1,4-ADDITION OF ARYLBORONIC ACIDS TO ALPHA,BETA-UNSATURATED CARBONYL COMPOUNDS. ALSO USED IN ASYMMETRIC HYDROGENATION OF N-ACYLATED BETA-DEHYDROAMINO ESTERS TO ENANTIOPURE BETA-AMINO ACID DERIVATIVES LEGAL INFORMATION: SOLD UNDER LICENSE FROM DSM FOR RESEARCH PURPOSES ONLY UNSPSC: 12352100 WGK: 3
Safety information
WGK Germany：	3

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