Basic Information |
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| Product Name： | (R)-C3-TUNEPHOS |
| CAS： | 486429-99-6 ;301847-89-2 |
| English Synonyms： | (S)-C3-TUNEPHOS ; (R)-C3-TUNEPHOS ; (S)-(+)-1,13-BIS(DIPHENYLPHOSPHINO)-7,8-DIHYDRO-6H-DIBENZO[F,H][1,5]DIOXONIN ; R-(-)-1,13-BIS(DIPHENYLPHOSPHINO)-7,8-DIHYDRO-6H-DIBENZO[F,H][1,5]DIOXONIN ; (S)-BIS(DIPHENYLPHOSPHINO)-7,8-DIHYDRO-6H-DIBENZO[F,H][1,5]DIOXONIN ; (R)-1,13-BIS(DIPHENYLPHOSPHINO)-7,8-DIHYDRO-6H-DIBENZO[F,H][1,5]DIOXONIN |
| MDL Number.： | MFCD06658115 |
| H bond acceptor： | 2 |
| H bond donor： | 0 |
| Smile： | c1ccc(cc1)P(c2ccccc2)c3cccc4c3-c5c(cccc5P(c6ccccc6)c7ccccc7)OCCCO4 |
| InChi： | InChI=1S/C39H32O2P2/c1-5-16-30(17-6-1)42(31-18-7-2-8-19-31)36-26-13-24-34-38(36)39-35(41-29-15-28-40-34)25-14-27-37(39)43(32-20-9-3-10-21-32)33-22-11-4-12-23-33/h1-14,16-27H,15,28-29H2 |
| InChiKey： | InChIKey=GTIXSUJKFAATAE-UHFFFAOYSA-N |
Property |
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| Comments： | APPLICATION: CHIRAL QUEST PHOSPHINE LIGANDS FOR ASYMMETRIC HYDROGENATIONREACTANT FOR: ASYMMETRIC HYDROGENATION OF KETONES WITH TUNEPHOS/DIAMINE/RUTHENIUM COMPLEXES STEREOSELECTIVE PREPARATION OF ARYLALKYL ESTERS VIA ENANTIOSELECTIVE HYDROGENATION OF ENOL ACETATES PRECATALYST FOR: ENANTIOSELECTIVE IRIDIUM-CATALYZED CARBONYL ALLYLATION FROM ALCOHOL OR ALDEHYDE BY TRANSFER HYDROGENATIVE COUPLING OF ALLYL ACETATE CATALYST FOR: ENANTIOSELECTIVE HYDROGENATION OF A-KETO ESTERS TO A-HYDROXY ESTERS USING RU-TUNEPHOS CATALYSTS APPLICATION: PROVIDES COMPARABLE OR SUPERIOR ENANTIOSELECTIVITIES AND CATALYTIC ABILITIES TO BINAP IN RU-CATALYZED ASYMMETRIC HYDROGENATIONS OF BETA-KETO ESTERS, CYCLIC BETA-(ACYLAMINO)ACRYLATES6 AND A-PHTHALIMIDE KETONES UNSPSC: 12352103 WGK: 3 |
Safety information |
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| WGK Germany： | 3 |
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