Basic Information |
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| Product Name： | (R,R,R)-(3,5-DIOXA-4-PHOSPHACYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS(1-PHENYLETHYL)AMINE |
| CAS： | 712352-08-4 ;415918-91-1 |
| English Synonyms： | (+)-N,N-BIS[(1R)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BS) ; (R)-2,2-BINAPHTHOYL-(S,S)-DI(1-PHENYLETHYL)AMINOYLPHOSPHINE ; (S,R,R)-(+)-(3,5-DIOXA-4-PHOSPHACYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS(1-PHENYLETHYL)AMINE ; (S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A;3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE, DICHLOROMETHANE ADDUCT ; (R,R,R)-(3,5-DIOXA-4-PHOSPHACYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS(1-PHENYLETHYL)AMINE |
| MDL Number.： | MFCD08561138 |
| H bond acceptor： | 3 |
| H bond donor： | 0 |
| Smile： | C[C@H](c1ccccc1)N([C@H](C)c2ccccc2)p3oc4ccc5ccccc5c4c6c7ccccc7ccc6o3 |
| InChi： | InChI=1S/C36H30NO2P/c1-25(27-13-5-3-6-14-27)37(26(2)28-15-7-4-8-16-28)40-38-33-23-21-29-17-9-11-19-31(29)35(33)36-32-20-12-10-18-30(32)22-24-34(36)39-40/h3-26H,1-2H3/t25-,26-/m1/s1 |
| InChiKey： | InChIKey=LKZPDRCMCSBQFN-CLJLJLNGSA-N |
Property |
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| Melting Point： | 102-103 DEG C |
| Comments： | APPLICATION: CHIRAL PHOSPHORAMIDITE LIGAND USED IN A HIGHLY ENANTIOSELECTIVE COPPER-CATALYZED CONJUGATE ADDITION OF DIAKYLZINCS TO A VARIETY OF MICHAEL ACCEPTORS. ALSO USED IN A PALLADIUM-CATALYZED DIETHYLZINC MEDIATED UMPOLUNG ALLYLATION APPLICATION: DSM MONOPHOS FAMILY OF HIGHLY EFFICIENT PRIVILEGED LIGANDS ASSAY METHOD: HPLC LEGAL INFORMATION: SOLD UNDER LICENSE FROM DSM FOR RESEARCH PURPOSES ONLY UNSPSC: 12352100 WGK: 3 |
Safety information |
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| WGK Germany： | 3 |
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中文版![(R,R,R)-(3,5-DIOXA-4-PHOSPHACYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS(1-PHENYLETHYL)AMINE](http://www.chemcd.com/createImage?smile=C%5BC%40H%5D%28c1ccccc1%29N%28%5BC%40H%5D%28C%29c2ccccc2%29p3oc4ccc5ccccc5c4c6c7ccccc7ccc6o3&size=web.jpg)