Basic Information |
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| Product Name： | 1,3-BIS(2,4,6-TRIMETHYLPHENYL)IMIDAZOLINIUM CHLORIDE |
| CAS： | 173035-10-4 |
| English Synonyms： | 4,5-DIHYDRO-1,3-BIS-(2,4,6-TRIMETHYLPHENYL)-1H-IMIDAZOLINIUM CHLORIDE ; 4,5-DIHYDRO-1,3-BIS(2,4,6-TRIMETHYLPHENYL)-1H-IMIDAZOLIUM CHLORIDE ; N,N'-(2,4,6-TRIMETHYLPHENYL)DIHYDROIMIDAZOLIUM CHLORIDE ; SIMES HCL ; 4,5-DIHYDRO-1,3-DIMESITYL-1H-IMIDAZOLIUM CHLORIDE ; 1,3-BIS-(2,4,6-TRIMETHYLPHENYL)-4,5-DIHYDRO-1H-IMIDAZOLIUM CHLORIDE ; 1,3-DIMESITYL-4,5-DIHYDRO-1H-IMIDAZOL-3-IUM CHLORIDE ; 1,3-DIMESITYLIMIDAZOLIDINIUM CHLORIDE ; 1,3-BIS(2,4,6-TRIMETHYLPHENYL)-4,5-DIHYDROIMIDAZOLIUM CHLORIDE ; 1,3-BIS(2,4,6-TRIMETHYLPHENYL)IMIDAZOLINIUM CHLORIDE ; 1,3-BIS(2,4,6-TRIMETHYLPHENYL)-IMIDAZOLIDINIUM-CHLORIDE ; 1,3-BIS-(2,4,6-TRIMETHYLPHENYL)-4,5-DIHYDRO-3H-IMIDAZOL-1-IUM CHLORIDE |
| MDL Number.： | MFCD09039279 |
| H bond acceptor： | 2 |
| H bond donor： | 0 |
| Smile： | Cc1cc(c(c(c1)C)N2CC[N+](=C2)c3c(cc(cc3C)C)C)C.[Cl-] |
| InChi： | InChI=1S/C21H27N2.ClH/c1-14-9-16(3)20(17(4)10-14)22-7-8-23(13-22)21-18(5)11-15(2)12-19(21)6;/h9-13H,7-8H2,1-6H3;1H/q+1;/p-1 |
| InChiKey： | InChIKey=COGMCBFILULEOS-UHFFFAOYSA-M |
Property |
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| Melting Point： | 280-286 DEG C/280-286 °C |
| Comments： | APPLICATION: N-HETEROCYCLIC CARBENE LIGANDS PRECURSOR TO AN N-HETEROCYCLIC CARBENE CATALYSTS USED FOR: A REGIOSELECTIVE CYCLOADDITON OF TERMINAL ACETYLENES WITH AZIDES LEADING TO 1,4-DISUBSTITUTEDTRIAZOLES. INTERNAL ACETYLENES CAN ALSO BE USED WITH THIS CATALYST. MARKOVNIKOV-TYPE HYDRATION OF TERMINAL ALKYNES. HYDROSILYLATION OF KETONES AND CYCLOADDITION OF AZIDES AND ALKYNES. SUZUKI-MIYAURA REACTIONS. LUMINESCENCE EXPERIMENTS UNSPSC: 12352100 WGK: 3 |
Safety information |
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| Symbol： |
GHS07
|
| Signal word： | Warning |
| Hazard statements： | H315-H319-H335 |
| Precautionary statements： | P261-P305 + P351 + P338 |
| hazard symbol： | Xi |
| Risk Code： | R:36/37/38 |
| Safe Code： | S:26-36 |
| WGK Germany： | 3 |
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