352655-61-9

(S)-(+)-2,2'-BIS[DI(3,5-DI-T-BUTYL-4-METHOXYPHENYL)PHOSPHINO]-6,6'-DIMETHOXY-1,1'-BIPHENYL

(S)-(+)-2,2'-BIS[DI(3,5-DI-T-BUTYL-4-METHOXYPHENYL)PHOSPHINO]-6,6'-DIMETHOXY-1,1'-BIPHENYL

CAS No.: 352655-61-9 ;910134-30-4
CCD No.: CCD00739298
Formula: C74 H104 O6 P2
MolWeight: 1151.58

Basic Information
Product Name：	(S)-(+)-2,2'-BIS[DI(3,5-DI-T-BUTYL-4-METHOXYPHENYL)PHOSPHINO]-6,6'-DIMETHOXY-1,1'-BIPHENYL
CAS：	352655-61-9 ;910134-30-4
English Synonyms：	(S)-[6,6'-DIMETHOXY(1,1'-BIPHENYL)-2,2'-DIYL]BIS[BIS[3,5-BIS(1,1-DIMETHYLETHYL)-4-METHOXYPHENYL]PHOSPHINE] ; SL-A109-2 ; (S)-(+)-2,2'-BIS[DI-(3,5-DI-T-BUTYL-4-METHOXY-PHENYL)PHOSPHINO]-(DIPHENYLPHOSPHINO)-6,6'-DIMETHOXY-1,1'-BIPHENYL ; SL-A109-1 ; (S)-(+)-2,2'-BIS[DI(3,5-DI-TERT-BUTYL-4-METHOXYPHENYL)PHOSPHINO]-6,6'-DIMETHOXY-1,1'-BIPHENYL ; (S)-(+)-2,2'-BIS[DI(3,5-DI-T-BUTYL-4-METHOXYPHENYL)PHOSPHINO]-6,6'-DIMETHOXY-1,1'-BIPHENYL ; (R)-(-)-2,2'-BIS[DI(3,5-DI-T-BUTYL-4-METHOXYPHENYL)PHOSPHINO]-6,6'-DIMETHOXY-1,1'-BIPHENYL ; (S)-(6,6'-DIMETHOXYBIPHENYL-2,2'-DIYL)BIS[BIS(3,5-DI-TERT-BUTYL-4-METHOXYPHENYL)PHOSPHINE] ; (R)-(-)-2,2'-BIS[DI(3,5-DI-TERT-BUTYL-4-METHOXYPHENYL)PHOSPHINO]-6,6'-DIMETHOXY-1,1'-BIPHENYL ; (R)-(6,6'-DIMETHOXYBIPHENYL-2,2'-DIYL)BIS[BIS(3,5-DI-TERT-BUTYL-4-METHOXYPHENYL)PHOSPHINE] ; (R)-3,5-T-BU-4-MEO-MEOBIPHEP ; (R)-[6,6'-DIMETHOXY(1,1'-BIPHENYL)-2,2'-DIYL]BIS[BIS[3,5-BIS(1,1-DIMETHYLETHYL)-4-METHOXYPHENYL]PHOSPHINE] ; (S)-3,5-T-BU-4-MEO-MEOBIPHEP
MDL Number.：	MFCD09265029
H bond acceptor：	6
H bond donor：	0
Smile：	CC(C)(C)c1cc(cc(c1OC)C(C)(C)C)P(c2cccc(c2c3c(cccc3P(c4cc(c(c(c4)C(C)(C)C)OC)C(C)(C)C)c5cc(c(c(c5)C(C)(C)C)OC)C(C)(C)C)OC)OC)c6cc(c(c(c6)C(C)(C)C)OC)C(C)(C)C
InChi：	InChI=1S/C74H104O6P2/c1-67(2,3)49-37-45(38-50(63(49)77-27)68(4,5)6)81(46-39-51(69(7,8)9)64(78-28)52(40-46)70(10,11)12)59-35-31-33-57(75-25)61(59)62-58(76-26)34-32-36-60(62)82(47-41-53(71(13,14)15)65(79-29)54(42-47)72(16,17)18)48-43-55(73(19,20)21)66(80-30)56(44-48)74(22,23)24/h31-44H,1-30H3
InChiKey：	InChIKey=JSSIQFXOSWLAGA-UHFFFAOYSA-N
Property
Comments：	APPLICATION: ATROPISOMERIC MEOBIPHEP LIGANDS. ASYMMETRICAL CONJUGATE ADDITION OF ARYLBORONIC ACIDS TO MALEIMIDES AND ENONES CATALYZED BY RHODIUM COMPLEXES. INTRAMOLECULAR KETONE HYDROACYLATION. DESYMMETRIZATION THROUGH ENANTIOSELECTIVE C-C BOND ACTIVATION AND RING EXPANSION OF ALLENYL CYCLOBUTANOLS. HYDROAMINATION OF BICYCLIC ALKENES AND DIENES WITH ANILINES. 1,4-ADDITION/ASYMMETRIC PROTONATION OF AMINO ACRYLATES GENERAL DESCRIPTION: SOLD IN COLLABORATION WITH SOLVIAS AG UNSPSC: 12352100 WGK: 3
Information：	OPTICAL PURITY: EE: =>99%
Safety information
WGK Germany：	3

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