basic_info |
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| Product_Name： | DIACETATO[(S)-(-)-5,5'-BIS[DI(3,5-XYLYL)PHOSPHINO]-4,4'-BI-1,3-BENZODIOXOLE]RUTHENIUM(II) |
| CAS： | 944450-50-4 ;944450-49-1 |
| EnglishSynonyms： | RU(OAC)2[(S)-DM-SEGPHOS(R)] ; DIACETATO[(S)-(-)-5,5'-BIS[DI(3,5-XYLYL)PHOSPHINO]-4,4'-BI-1,3-BENZODIOXOLE]RUTHENIUM(II) ; RU(OAC)2[(R)-DM-SEGPHOS(R)] ; (R)-RU(OAC)2(DM-SEGPHOS(R)) ; DIACETATO[(R)-5,5'-BIS[DI(3,5-XYLYL)PHOSPHINO]-4,4'-BI-1,3-BENZODIOXOLE]RUTHENIUM(II) ; (S)-RU(OAC)2(DM-SEGPHOS(R)) ; DIACETATO[(R)-(+)-5,5'-BIS[DI(3,5-XYLYL)PHOSPHINO]-4,4'-BI-1,3-BENZODIOXOLE]RUTHENIUM(II) |
| pro_mdlNumber： | MFCD09753025 |
| pro_acceptors： | 4 |
| pro_donors： | 0 |
| pro_smile： | Cc1cc(cc(c1)P(c2ccc3c(c2c4c(ccc5c4OCO5)P(c6cc(cc(c6)C)C)c7cc(cc(c7)C)C)OCO3)c8cc(cc(c8)C)C)C.CC(=O)O[Ru]OC(=O)C |
| InChi： | InChI=1S/C46H44O4P2.2C2H4O2.Ru/c1-27-13-28(2)18-35(17-27)51(36-19-29(3)14-30(4)20-36)41-11-9-39-45(49-25-47-39)43(41)44-42(12-10-40-46(44)50-26-48-40)52(37-21-31(5)15-32(6)22-37)38-23-33(7)16-34(8)24-38;2*1-2(3)4;/h9-24H,25-26H2,1-8H3;2*1H3,(H,3,4);/q;;;+2/p-2 |
| InChiKey： | InChIKey=ACKYBTAGKAINOG-UHFFFAOYSA-L |
property |
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| Comments： | APPLICATION: CATALYST FOR: STEREOSELECTIVE PREPARATION OF BETA-AMINO AMIDES VIA RUTHENIUM SEGPHOS COMPLEX-CATALYZED ASYMMETRIC REDUCTIVE AMINATION OF BETA-KETO AMIDES APPLICATION: TAKASAGO LIGANDS AND COMPLEXES FOR ASYMMETRIC REACTIONS LEGAL INFORMATION: SEGPHOS IS A REGISTERED TRADEMARK OF TAKASAGO INTL CORP LEGAL INFORMATION: SOLD IN COLLABORATION WITH TAKASAGO FOR RESEARCH PURPOSES ONLY. JP REGISTRATION NO 3148136 STORAGE TEMPERATURE: 2-8 DEG C UNSPSC: 12352103 |
secure_info |
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| secure_symbol： |
GHS07
|
| secure_signal_word： | Warning |
| secure_risk_stmt： | H315-H319-H335 |
| secure_cautionary_stmt： | P261-P305 + P351 + P338 |
| secure_damage_code： | Xi |
| secure_risk_disclosure_stmt： | R:36/37/38 |
| secure_security_stmt： | S:26 |
| secure_wgk_germany： | 3 |
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