Basic Information |
|
| Product Name： | DICHLORO[(R)-(+)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]-1,1'-BINAPHTHYL][(2R)-(-)-1,1-BIS(4-METHOXYPHENYL)-3-METHYL-1,2-BUTANEDIAMINE]RUTHENIUM(II) |
| CAS： | 220114-32-9 |
| English Synonyms： | DICHLORO[(R)-(+)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]-1,1'-BINAPHTHYL][(2R)-(-)-1,1-BIS(4-METHOXYPHENYL)-3-METHYL-1,2-BUTANEDIAMINE]RUTHENIUM(II) ; RUCL2[(R)-XYLBINAP][(R)-DAIPEN] ; DICHLORO[(R)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]-1,1'-BINAPHTHYL][(2R)-1,1-BIS(4-METHOXYPHENYL)-3-METHYL-1,2-BUTANEDIAMINE]RUTHENIUM(II) ; RUCL2[(R)-DM-BINAP][(R)-DAIPEN] |
| MDL Number.： | MFCD09753026 |
| H bond acceptor： | 0 |
| H bond donor： | 0 |
| Smile： | Cc1cc(cc(c1)P(c2ccc3ccccc3c2c4c5ccccc5ccc4P(c6cc(cc(c6)C)C)c7cc(cc(c7)C)C)c8cc(cc(c8)C)C)C.CC(C)[C@H](C(c1ccc(cc1)OC)(c2ccc(cc2)OC)N)N.Cl[Ru]Cl |
| InChi： | InChI=1S/C52H48P2.C19H26N2O2.2ClH.Ru/c1-33-21-34(2)26-43(25-33)53(44-27-35(3)22-36(4)28-44)49-19-17-41-13-9-11-15-47(41)51(49)52-48-16-12-10-14-42(48)18-20-50(52)54(45-29-37(5)23-38(6)30-45)46-31-39(7)24-40(8)32-46;1-13(2)18(20)19(21,14-5-9-16(22-3)10-6-14)15-7-11-17(23-4)12-8-15;;;/h9-32H,1-8H3;5-13,18H,20-21H2,1-4H3;2*1H;/q;;;;+2/p-2/t;18-;;;/m.1.../s1 |
| InChiKey： | InChIKey=UTQCNMRDWASSEC-OEGAAENXSA-L |
Property |
|
| Melting Point： | 197-211 DEG C |
| Comments： | APPLICATION: CATALYST FOR: NOYORI-TYPE ENANTIOSELECTIVE KETONE HYDROGENATION. ENANTIOSELECTIVE AND ASYMMETRIC HYDROGENATION OF KETONES APPLICATION: TAKASAGO LIGANDS AND COMPLEXES FOR ASYMMETRIC REACTIONS LEGAL INFORMATION: SOLD IN COLLABORATION WITH TAKASAGO FOR RESEARCH PURPOSES ONLY. JP REGISTRATION NO 2041996, 2731377, 2935453 JP APPLICATION NO 19970359654 STORAGE TEMPERATURE: 2-8 DEG C UNSPSC: 12352103 |
Safety information |
|
* If the product has intellectual property rights, a license granted is must or contact us.
2010-2025 © Chemical Cloud Database. ALL Rights Reserved.浙ICP备11020424号-1
浙公网安备 33010802004002号
中文版![DICHLORO[(R)-(+)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]-1,1'-BINAPHTHYL][(2R)-(-)-1,1-BIS(4-METHOXYPHENYL)-3-METHYL-1,2-BUTANEDIAMINE]RUTHENIUM(II)](http://www.chemcd.com/createImage?smile=Cc1cc%28cc%28c1%29P%28c2ccc3ccccc3c2c4c5ccccc5ccc4P%28c6cc%28cc%28c6%29C%29C%29c7cc%28cc%28c7%29C%29C%29c8cc%28cc%28c8%29C%29C%29C.CC%28C%29%5BC%40H%5D%28C%28c1ccc%28cc1%29OC%29%28c2ccc%28cc2%29OC%29N%29N.Cl%5BRu%5DCl&size=web.jpg)