Basic Information |
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| Product Name： | (R,R)-1,3-BIS[(4-BROMOPHENYL)METHYL]-2-CHLOROOCTAHYDRO-2-ALLYL-1H-1,3,2-BENZODIAZASILOLE |
| CAS： | 546084-25-7 |
| English Synonyms： | (1R,2R)-[1,2-CYCLOHEXANEDIAMINO-N,N'-BIS(4-BROMOBENZYL)ALLYLCHLOROSILANE] ; (R,R)-1,3-BIS[(4-BROMOPHENYL)METHYL]-2-CHLOROOCTAHYDRO-2-ALLYL-1H-1,3,2-BENZODIAZASILOLE ; (3AR,7AR)-2-ALLYL-1,3-BIS(4-BROMOBENZYL)-2-CHLOROOCTAHYDRO-1H-BENZO[D][1,3,2]DIAZASILOLE |
| MDL Number.： | MFCD10567380 |
| H bond acceptor： | 2 |
| H bond donor： | 0 |
| Smile： | C=CC[Si]1(N([C@@H]2CCCC[C@H]2N1Cc3ccc(cc3)Br)Cc4ccc(cc4)Br)Cl |
| InChi： | InChI=1S/C23H27Br2ClN2Si/c1-2-15-29(26)27(16-18-7-11-20(24)12-8-18)22-5-3-4-6-23(22)28(29)17-19-9-13-21(25)14-10-19/h2,7-14,22-23H,1,3-6,15-17H2/t22-,23-/m1/s1 |
| InChiKey： | InChIKey=JTYONYYNZDUUGN-DHIUTWEWSA-N |
Property |
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| Melting Point： | 95-100 DEG C |
| Physical Property： | FLASHPOINT: >110 DEG C FLASHPOINT: >230 DEG F |
| Comments： | APPLICATION: AN OPERATIONALLY SIMPLE REGIOSELECTIVE AND ENANTIOSELECTIVE ALLYLATION OF BETA-DIKETONES TO PROVIDE TERTIARY CARBINOLS APPLICATION: LEIGHTON'S STRAINED SILACYCLES: POWERFUL ENANTIOSELECTIVE ALLYLATION REAGENTS. ENANTIOSELECTIVE ALLYLATION OF ALDEHYDES LEGAL INFORMATION: US PATENT NO 7,534,905 OPTICAL ACTIVITY: [ALPHA]22/D -53.0 DEG, C = 1 IN CHLOROFORM RIDADR: UN 3131 4.3/PG 3 STORAGE TEMPERATURE: 2-8 DEG C WGK: 1 |
Safety information |
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| Symbol： |
GHS02
GHS05
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| Signal word： | Danger |
| Hazard statements： | H261-H314 |
| Precautionary statements： | P231 + P232-P280-P305 + P351 + P338-P310-P422 |
| hazard symbol： | F,C |
| Risk Code： | R:15-34 |
| Safe Code： | S:26-36/37/39-43-45 |
| WGK Germany： | 1 |
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中文版![(R,R)-1,3-BIS[(4-BROMOPHENYL)METHYL]-2-CHLOROOCTAHYDRO-2-ALLYL-1H-1,3,2-BENZODIAZASILOLE](http://www.chemcd.com/createImage?smile=C%3DCC%5BSi%5D1%28N%28%5BC%40%40H%5D2CCCC%5BC%40H%5D2N1Cc3ccc%28cc3%29Br%29Cc4ccc%28cc4%29Br%29Cl&size=web.jpg)