Basic Information |
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| Product Name： | [(R)-(+)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL]PALLADIUM(II) CHLORIDE |
| CAS： | 215597-19-6 ;191654-69-0 |
| English Synonyms： | PALLADIUM, [(1S)-[1,1'-BINAPHTHALENE]-2,2'-DIYLBIS[BIS(4-METHYLPHENYL)PHOSPHINE-KAPPAP]]DICHLORO-, (SP-4-2)- ; [(R)-(+)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL]PALLADIUM(II) CHLORIDE ; [(S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL]PALLADIUM(II) CHLORIDE ; [PDCL2[(S)-4-TOLYLBINAP]] ; [PDCL2[(R)-4-TOLYLBINAP]] |
| MDL Number.： | MFCD11656205 |
| H bond acceptor： | 0 |
| H bond donor： | 0 |
| Smile： | Cc1ccc(cc1)P(c2ccc(cc2)C)c3ccc4ccccc4c3c5c6ccccc6ccc5P(c7ccc(cc7)C)c8ccc(cc8)C.Cl[Pd]Cl |
| InChi： | InChI=1S/C48H40P2.2ClH.Pd/c1-33-13-23-39(24-14-33)49(40-25-15-34(2)16-26-40)45-31-21-37-9-5-7-11-43(37)47(45)48-44-12-8-6-10-38(44)22-32-46(48)50(41-27-17-35(3)18-28-41)42-29-19-36(4)20-30-42;;;/h5-32H,1-4H3;2*1H;/q;;;+2/p-2 |
| InChiKey： | InChIKey=ADMKISPNGKUJAU-UHFFFAOYSA-L |
Property |
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| Melting Point： | >300 DEG C |
| Comments： | APPLICATION: CATALYST FOR: ENANTIOSELECTIVE PREPARATION OF HYDROXYDICARBONYLS VIA ALDOL ADDITION OF PYRUVATES AND DIKETONES WITH KETENE THIOACETAL STEREOSELECTIVE ALDOL CONDENSATION USING TRIMETHYL[[(PHENYL)ETHENYL]OXY]SILANE AND BENZALDEHYDE AS REACTANTS STEREOSELECTIVE PREPARATION OF NAPHTHALENOLS VIA ALKYLATIVE RING OPENING OF OXABENZONORBORNADIENES WITH DIALKYLZINC REACTANT FOR: PREPARATION OF PALLADIUM BIS(DIPHENYLPHOSPHINO)BINAPHTHYL AQUA MONONUCLEAR AND HYDROXO-BRIDGED DINUCLEAR COMPLEXES WGK: 3 |
Safety information |
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| Symbol： |
GHS07
|
| Signal word： | Warning |
| Hazard statements： | H302 + H312 + H332-H315-H319-H335 |
| Precautionary statements： | P261-P280-P305 + P351 + P338 |
| hazard symbol： | Xn |
| Risk Code： | R:20/21/22-36/37/38 |
| Safe Code： | S:26 |
| WGK Germany： | 3 |
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中文版![[(R)-(+)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL]PALLADIUM(II) CHLORIDE](http://www.chemcd.com/createImage?smile=Cc1ccc%28cc1%29P%28c2ccc%28cc2%29C%29c3ccc4ccccc4c3c5c6ccccc6ccc5P%28c7ccc%28cc7%29C%29c8ccc%28cc8%29C.Cl%5BPd%5DCl&size=web.jpg)