Basic Information |
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| Product Name： | (2S,2'S)-(-)-[N,N'-BIS(2-PYRIDYLMETHYL)]-2,2'-BIPYRROLIDINEBIS(ACETONITRILE)IRON(II) HEXAFLUOROANTIMONATE |
| CAS： | 959395-10-9 |
| English Synonyms： | FE(S,S-PDP) HEXAFLUOROANTIMONATE ; WHITE-CHEN CATALYST ; (2S,2'S)-(-)-[N,N'-BIS(2-PYRIDYLMETHYL)]-2,2'-BIPYRROLIDINEBIS(ACETONITRILE)IRON(II) HEXAFLUOROANTIMONATE ; [FE(S,S-PDP)(CH3CN)2](SBF6)2 ; IRON(II) (S,S)-(2-([(S)-2-[(S)-1-(PYRIDIN-2-YLMETHYL)PYRROLIDIN-2-YL]PYRROLIDIN-1-YL]METHYL)PYRIDINE)(BIS-ACETONITRILE) HEXAFLUOROANTIMONATE ; FE(S,S-PDP) ; WHITE CATALYST |
| MDL Number.： | MFCD16038114 |
| H bond acceptor： | 4 |
| H bond donor： | 0 |
| Smile： | CC#N.CC#N.c1ccnc(c1)CN2CCC[C@H]2[C@@H]3CCCN3Cc4ccccn4.F[Sb-](F)(F)(F)(F)F.F[Sb-](F)(F)(F)(F)F.[Fe+2] |
| InChi： | InChI=1S/C20H26N4.2C2H3N.12FH.Fe.2Sb/c1-3-11-21-17(7-1)15-23-13-5-9-19(23)20-10-6-14-24(20)16-18-8-2-4-12-22-18;2*1-2-3;;;;;;;;;;;;;;;/h1-4,7-8,11-12,19-20H,5-6,9-10,13-16H2;2*1H3;12*1H;;;/q;;;;;;;;;;;;;;;+2;2*+5/p-12/t19-,20-;;;;;;;;;;;;;;;;;/m0................./s1 |
| InChiKey： | InChIKey=XUNWHBGEOCZDBX-CGOGJHNFSA-B |
Property |
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| Melting Point： | >300 DEG C |
| Comments： | APPLICATION: CATALYST FOR: OXIDATIVE RADICAL REACTIONS. SELECTIVE OXIDATION OF ALKYL CARBON-HYDROGEN BONDS. METHYLENE GROUP OXIDATION OPTICAL ACTIVITY: [ALPHA]20/D -30.0 TO -20.0 DEG, C = 0.2 IN ACETONITRILE |
Safety information |
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| Symbol： |
GHS07
|
| Signal word： | Warning |
| Hazard statements： | H315-H319-H335 |
| Precautionary statements： | P261-P305 + P351 + P338 |
| hazard symbol： | Xi |
| Risk Code： | R:36/37/38 |
| Safe Code： | S:26 |
| WGK Germany： | 3 |
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中文版![(2S,2'S)-(-)-[N,N'-BIS(2-PYRIDYLMETHYL)]-2,2'-BIPYRROLIDINEBIS(ACETONITRILE)IRON(II) HEXAFLUOROANTIMONATE](http://www.chemcd.com/createImage?smile=CC%23N.CC%23N.c1ccnc%28c1%29CN2CCC%5BC%40H%5D2%5BC%40%40H%5D3CCCN3Cc4ccccn4.F%5BSb-%5D%28F%29%28F%29%28F%29%28F%29F.F%5BSb-%5D%28F%29%28F%29%28F%29%28F%29F.%5BFe%2B2%5D&size=web.jpg)