(+)-B-METHOXYDIISOPINOCAMPHEYLBORANE ,99438-28-5

(+)-B-METHOXYDIISOPINOCAMPHEYLBORANE

Basic Information
Product Name：	(+)-B-METHOXYDIISOPINOCAMPHEYLBORANE
CAS：	99438-28-5 ;85134-98-1
English Synonyms：	(+)-B-METHOXYDIISOPINOCAMPHEYLBORANE ; (+)-BETA-METHOXYDIISOPINOCAMPHEYL-BORANE ; (+)-DIISOPINOCAMPHEYLMETHOXYBORANE ; (-)-B-METHOXYDIISOPINOCAMPHEYLBORANE HYDRATE 97+%
MDL Number.：	MFCD21332906
H bond acceptor：	1
H bond donor：	0
Smile：	B([C@H]1C[C@H]2C[C@@H]([C@@H]1C)C2(C)C)([C@H]3C[C@H]4C[C@@H]([C@@H]3C)C4(C)C)OC
InChi：	InChI=1S/C21H37BO/c1-12-16-8-14(20(16,3)4)10-18(12)22(23-7)19-11-15-9-17(13(19)2)21(15,5)6/h12-19H,8-11H2,1-7H3/t12-,13-,14+,15+,16-,17-,18-,19-/m0/s1
InChiKey：	InChIKey=IAQXEQYLQNNXJC-JPDDNCELSA-N
Property
Physical Property：	FLASHPOINT: 113 DEG C FLASHPOINT: 235.4 DEG F
Comments：	APPLICATION: BOTH (+)- AND (-)-FORMS ARE PRECURSORS TO B-ALLYLDIISOPINOCAMPHEYLBORANE DERIVATIVES, WHICH ARE SUBSEQUENTLY REACTED WITH ALDEHYDES TO GIVE HOMOALLYLIC ALCOHOLS AND BETA-AMINO ALCOHOLS OF HIGH ENANTIOMERIC EXCESS APPLICATION: REACTANT INVOLVED IN: OXIDATIVE CYCLIZATION AND ALKYLATION FOR SYNTHESIS OF IONOMYCIN. INTRAMOLECULAR CONJUGATE ADDITION FOR TETRAHYDROPYRAN SYNTHESIS. ALDOL ADDITION AND SUZUKI COUPLING REACTIONS. ALLYLATION. SYNTHESIS OF ALKANOLS UNSPSC: 12352100 WGK: 3
Safety information
Symbol：	GHS07
Signal word：	Warning
Hazard statements：	H315-H319-H335
Precautionary statements：	P261-P305 + P351 + P338
hazard symbol：	Xi
Risk Code：	R:36/37/38
Safe Code：	S:26-36
WGK Germany：	3

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